gizmo_2655 wrote on Feb 26
th, 2011 at 9:45pm:
Ok, go for it...convince me that Co2 or GHG's cause warming...
Let's start with an overview of the Earth's energy balance.
Most of the UV, visible and IR energy from the Sun passes right through the Earth's atmosphere and is absorbed by its surface (some is reflected and never absorbed). That energy heats the Earth surface to a average temperature of 18 degrees C. This temperature is sufficient for the Earth to emit energy only in the Long Wave IR part of the spectrum. It is this outgoing IR energy that is absorbed by the greenhouse gases. They warm the atmosphere and re-direct the IR energy, rather than allowing it to pass uninterrupted back to space.
Obviously there are many different factors that determine the average temperature of the Earth. These include the energy that the Earth receives from the sun, the amount of energy reflected back into space by clouds, ice and other bright substances, and conversely the amount of energy absorbed by darker surfaces, such as pine forests. That's known as the Albedo effect.
There are slow cyclic changes in the Earth's orbit and tilt that cause changes to the amount of energy being received from the sun. These effects are collectively referred to as the Milankovich cycles, after the Serbian engineer Milutin Milankovich who first described them. I could describe these effects in more detail, but Wikipedia beat me to it:
http://en.wikipedia.org/wiki/Milankovitch_cyclesThere are also factors that determine changes in local temperatures on the globe over time. These include changes in ocean (eg the SOI) and air circulation, and the melting of glaciers etc.
Now getting back to the Greenhouse effect, we have the energy radiated from the Earth at around 10 microns. Coincidentally (and lucky for us), carbon dioxide and water vapour happen to absorb Infrared at around that wavelength.
I keep harping back to this diagram, but it's the key to understanding the Greenhouse effect.

You need to look at the graphs one by one. The first one (red area) illustrates how energy is received from the sun and some is re-radiated back into space. 70 - 75% of the mostly visible and a bit of near infrared is absorbed by the Earth.
On the same graph, the blue area shows the 'black body" radiation from the Earth (remember we talked about the Stefan Boltzmann equation?). Between 15 and 30% of that energy is transmitted into space at any given time.
Now the next graph down shows the total absorption and scattering. Notice that there is a huge chunk missing around the LWIR peak at 10 microns? (This can actually be measured directly by the way). What do you think causes that absorption? The key is the graphs underneath that show the different components.
Have you ever seen the actual spectrum caused by different sources? For example the sodium spectrum is not continuous. (Remember the old sodium vapour street lamps ? They gave off a yellow light) It's a series of lines, but as the intensity of the source is increased, the lines broaden with width. A similar thing happens with an absorption spectrum. We'll talk about that more later.